A spokesperson for the Hollywood power couple confirmed the long-time lovers tied the knot in a ceremony in France on Saturday.
The pair, who first met on the set of Mr & Mrs Smith in 2004, wed in France on Saturday, their spokesperson confirmed.
The couple arrived in Nice on Saturday and are thought to have married at Chateau Mitaval.
Details of the ceremony are being kept under wraps but Angelina previously admitted the couple’s children were going to plan their nuptials.
She explained: “They will in a way be the wedding planners. It’s going to be Disney or paintball – one or the other! We’ve got a lot of different personalities in the house.
“They’ve got some strong opinions. It will be fun. That’s the important thing. When we do it, it will feel like a great day for our family.”
And their well-kept secret had quite the reaction on Twitter.
While some asked how they managed to keep it under wraps since Saturday, others were miffed the actor was finally off the market.
One user wrote: “BRAD AND ANGE. MARRIED. WHAT?? I go out for lunch and this happens.”
And the jokers: “I tweeted Angelina Jolie last week telling her our affair had to end. Co-incidence?”
“Brad Pitt off the market. Cheers Ange… way to ruin my day,” posted another.